Surfactants (surface acting agents), also called wetting agents and spreaders, physically change the surface tension of a spray droplet. For a pesticide to perform its function properly on a plant, the spray droplet must be able to wet the foliage and spread out evenly. Surfactants make the area of pesticide coverage larger, which increases the pest's exposure to the chemical (see Figure 1). Surfactants are particularly useful when applying a pesticide to a plant with waxy or hairy leaves. Without proper wetting and spreading, spray droplets often run off or fail to provide good coverage to the surfaces. Too much surfactant, however, can cause excessive runoff, which may make the pesticide less effective.
CLASSIFICATION OF SURFACTANTS
Surfactants are classified by the way they ionize, or split apart, into electronically charged molecules called ions. Use only the type as directed on the label.
Anionic Surfactants (negative charge)
- Most effective when used with contact pesticides
Cationic Surfactants (positive charge)
- Should never be used as standalone surfactant because they are usually phytotoxic (poisonous to plants)
Nonionic Surfactants (no charge)
- Composed of alcohols and/or fatty acids and are compatible with most pesticides
- Pesticidal activity can be quite different from that of anionic or cationic surfactants
- Helps pesticide sprays penetrate plant cuticles
- Often used with systemic pesticides
- Most registered pesticides that require using a surfactant recommend this type
Organo-silicone Surfactants (a newer group taking the place of nonionic surfactants)
- Reduces surface tension, increases spreading ability, and improves rainfastness (amount of time between pesticide application and rainfall)
Keep in mind that selecting the wrong surfactant can reduce the effectiveness of a pesticide product and increase the risk of plant injury.
Oils are being used to control grassy weeds. The three types of oil-based adjuvants include crop oils, crop oil concentrates, and vegetable oil concentrates.
Crop oil is generally 95 to 98 percent paraffin or naptha-based petroleum oil with 1 to 2 percent surfactant/emulsifier. Crop oils promote the penetration of a pesticide spray either through a plant's waxy cuticle or through an insect's tough, chitinous shell. Traditional crop oils are more commonly used for insect and disease control and
rarely with herbicides.
Crop oil concentrates (COCs) are made up of 80 to 85 percent emulsifiable petroleum-based oil and 15 to 20 percent nonionic surfactant. Crop oil concentrates have the penetration properties of oil and the spreading properties of a surfactant. COCs are often used with postemergence herbicides.
Vegetable oil concentrates (VOCs) are made up of 80 to 85 percent crop derived seed oil (usually cotton, linseed, soybean, or sunflower oil) and 15 to 20 percent nonionic surfactant. To improve their performance, many VOCs have undergone a process called esterification, which increases the oil-loving characteristics of the seed oil and results in a methylated seed oil (MSO). MSOs work the same as traditional crop oil concentrates to increase penetration of the pesticide into the target pest.
Improved herbicide activity has been shown by adding ammonium sulfate or urea-ammonium nitrate to the spray mixture. Nitrogen fertilizers may replace some adjuvants but are usually included in addition to a surfactant and a crop oil concentrate for use with systemic pesticide products. Many fertilizer-based adjuvants are available in liquid forms, which are easier to mix and provide more consistent results. Fertilizers should only be used with herbicides when recommended by the label.
Special purpose/utility adjuvants
Special purpose adjuvants fix specific conditions that can affect the spray solution or the actual application of the pesticide in a negative way. By controlling these factors, you can maximize the efficient use of the pesticide. Compatibility agents, buffering and conditioning agents, defoaming agents, deposition agents (stickers), and drift control agents and thickeners modify the physical characteristics of the spray solution. Foam markers, tank cleaners, colorants, and suspension agents help minimize application problems. Carefully follow product label directions before adding any adjuvant to a spray mix.
Pesticides are commonly mixed with liquid fertilizers or other pesticides. However, some combinations can be physically or chemically incompatible, causing clumps and uneven distribution in the spray tank. Occasionally, the incompatible mixture will clog the pump and hoses, resulting in expensive cleanup and repairs. Using a compatibility agent may eliminate these problems. A "jar test" can help determine the stability of the mixture.
JAR TEST FOR COMPATIBILITY OF PESTICIDE MIXTURES
Always wear personal protective equipment (PPE) when pouring or mixing pesticides, even for this simple test.
To conduct a jar test, add proportionate amounts of all the products you intend to mix in the spray tank to a clear quart jar. When using a liquid fertilizer carrier, many herbicide labels recommend using two jars for this test--one with and one without a compatibility agent.
Step 1. Measure 1 pint of water (or carrier solution) into a clear quart jar. Use the same water source that will be used in the tank mix.
Step 2. Add proportionate amounts of each product, one at a time, in the order suggested on the label, or add ingredients in the following order. Stir each time a formulation has been added.
- Compatibility, buffering, or defoaming agents (if needed)
- Wettable powders, dry flowables, water-dispersible granule products
- Flowables, liquids, microencapsulated products
- Solutions, soluble powder products
- Remaining adjuvants, such as surfactants or crop oils (if needed)
- Emulsifiable concentrates
Step 3. Shake the jar vigorously and allow it to stand for at least 15 minutes. The mixture is probably not compatible if scum forms on the surface, the mixture clumps, or any solids settle to the bottom (except for wettable powders). Do not use a mixture that gives off heat (determined by feeling the jar) as that indicates a chemical reaction has occurred and changed the chemical properties of the products.
If a compatibility problem occurs, dispose of the mixture according to the pesticide product label. Finally, if no signs of incompatibility appear, put the pesticide test mixture into the spray tank. In addition, rinse all utensils and pour the rinse water (rinsate) into the spray tank and apply to a labeled site. Do not use utensils or jars for any other purpose after they have contacted pesticides.
BUFFERING AND CONDITIONING AGENTS
Most herbicides, insecticides, and fungicides perform best in slightly acidic water with a pH of 4.0 to 6.5 with the exception of sulfonylurea herbicides, which perform better in water with a pH of 7.0 or above. Pesticide solutions above pH 7.0 are at greater risk of degrading or breaking down. In some cases, a pesticide that is stable when the water pH is 5.0, but will lose half of it's effectiveness in as little as 15 minutes if the pH of the water is 9.0. Acidifier adjuvants lower the pH of the water in the spray tank, although they do not necessarily maintain a constant pH level. Buffers tend to stabilize the pH at a relatively constant level.
Conditioning or water-softening agents reduce problems caused by hard water. Hard water minerals, especially calcium and magnesium ions, bind with active ingredients of some pesticides, which may decrease pesticide performance. Before using a buffer or conditioning agent, consider the specific pesticide requirements and test the water for pH and hardness. Also, refer to the pesticide label for precautions and recommendations.
Some pesticide formulations create foam or a frothy head in some spray tanks. This is often the result of the type of surfactant used in the formulation and the type of spray tank agitation system. The foam usually can be reduced or eliminated by adding a small amount of a defoaming agent.
These adjuvants, which are often referred to as "stickers," increase the ability of solid particles to stick to the target surface. These adjuvants can decrease the amount of pesticide that washes off during irrigation or rain. Deposition agents can also reduce evaporation of the pesticide and some can slow degradation of pesticides by ultraviolet rays. Many deposition agents also include a wetting agent to make a general purpose product that both spreads and sticks to the target surface.
DRIFT CONTROL AGENTS AND THICKENERS
Drift is a function of droplet size, wind speed, and height of the spray boom. Small droplets (with diameters of 150 microns or less) tend to drift away from targeted areas. Drift retardants or deposition aids improve on-target placement of the pesticide spray by increasing the average droplet size. Drift reduction is a priority near sensitive sites or when conditions warrant extra precaution. Using a spray drift agent may be well worth the small reduction in the effectiveness of the application that can result from the change in droplet size.
Thickeners, as the name suggests, increase the viscosity of spray mixtures. These adjuvants are used to control drift or slow evaporation after the spray has been deposited on the target area. Slowing evaporation is important when using systemic pesticides because they can penetrate the plant cuticle only as long as they remain wet. Once the water has evaporated, any unabsorbed pesticide will remain on the leaf surface and can only be taken up by the plant if it returns to an absorbable state by rewetting.
Foam markers are designed to produce foam when used in conjunction with special equipment to leave a "trail" of where the product was applied. This helps the applicator avoid skips and overlapping areas.
Commercial tank cleaners are designed to work with water and oil soluble pesticide products and are often recommended on pesticide labels. Always refer to the label for recommended tank cleaners with the product being used. Always follow label directions and wear personal protective equipment when cleaning a sprayer.
Colorants are used to alter the color of spray solutions to visually aid in the placement of the spray solution.
These products extend the amount of time a pesticide will remain in suspension. If agitation is stopped for a time, upon restarting the agitation, this product aids in re-suspending the mixture.
How to Choose the Right Adjuvant
Many factors must be considered when choosing an adjuvant for use in a pest management program. The following are some guidelines:
- First and foremost, read the pesticide label.
- Use only adjuvants manufactured and marketed for agricultural or horticultural uses. Do not use industrial products or household detergents with pesticides because they may interfere with or reduce pesticide performance.
- Pesticide labels seldom mention specific brands of adjuvants, but rather the general type of adjuvant, such as nonionic surfactant, crop oil, or defoaming agent. However, if the pesticide label lists a specific brand of adjuvant, that brand must be used. Any substitution would be a violation of the label.
- Miracle adjuvants do not exist. Ignore claims such as "keeps spray equipment clean," or "causes better root penetration." Always buy recognizable, name-brand products from a reputable dealer.
- Adjuvant recommendations may change due to changes in pesticide formulations, newly labeled tank mixes and premixes, and changes in application technology and procedures. Always read the label every time a pesticide product is used.
- Using an adjuvant is not always necessary. Knowing when not to use an adjuvant is just as important as knowing when to use one. If the pesticide label does not mention an adjuvant, the manufacturer's research probably has shown no benefits--or even adverse effects--from adjuvant use.
Spray adjuvants can play a major role in safe and effective pest control when used as recommended on the label. Although a single adjuvant may perform more than one function, no single product can solve every problem. As a result, many spray adjuvants are available, each formulated to solve problems associated with a particular type of application. Read the pesticide label.
The correct use of adjuvants does require knowledge of the site you plan to spray, the target pest, your equipment, and, of course, the pesticide you plan to use. By knowing the particular needs and limitations of the products you intend to use, adjuvants can prove to be a positive addition to the spray tank.